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HOW TO install Ubuntu - complete guide
List of everyday used applications (in process)

This is the method I used to change from nf4 mainboard integrated audio to Live Value soundcard but I think it should work with any combination of soundcards. If it doesn't leave a comment and I'll change this text.
In terminal (Alt+F2 -> gnome-terminal) type:
sudo asoundconf list
This will list sound cards you have in your computer.

To switch to another card type:
sudo asoundconf set-default-card CARDNAME
Where CARDNAME is the name of sound card you wish to use.
For example:

Reboot computer after that and after that select the card in System>Preferences>Sound
